Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites. 相似文献
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions. 相似文献
The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH4)2SO4] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture. 相似文献
AbstractLarge debris flows in steep-sloped ravines debouching to the Rimac River, in metropolitan Lima (Peruvian capital), have resulted in considerable loss of life and property adversely impacting communities in the region. Temporal, spatial and volumetric features of debris flows are difficult to predict, and it is of utmost importance that achievable management solutions are found to reduce the impact of these catastrophic events. The emotional and economic toll of these debris flows on this increasingly densely populated capital city in South America is devastating where communities must live in such inadequate and dangerous conditions. To address this problem, the application of advanced Japanese technology, Sustainable Actions Basin Orientation (SABO), has been investigated using a geomorphological modelling to develop an implementation plan. Rayos de Sol stream basin in Chosica, was selected as a pilot to develop the proposal, as it is considered high risk due to the presence of ancient debris flows and recent flows in 2012, 2015 and 2017. The recurrence of debris flows in this location has resulted in numerous deaths and catastrophic property losses. This study combines geologic and geomorphic mapping and hydraulic and landform evolution numerical modelling. The implementation of a SABO Master Plan based on the multidisciplinary assessment hazard scenarios, will allow the implementation of feasible mitigation actions. The SABO technology has been applied successfully in Japan and other countries in areas with steep short slopes, similar to the conditions surrounding the Peruvian capital. Results from this study will be presented to the Peruvian Government as part of an action plan to manage debris-flow impact.
KEY POINTS
High-risk mass slope failure is linked to poor urban planning in urban developing regions of Lima the capital of Peru.
A multidisciplinary study including geotechnical and hydrological analysis, engineering design, and socio-economic research is required to implement a SABO Master Plan, and this basin is pilot study basin.
At the present time, a maintenance programme for existing hydraulic structures should be implemented, and a flood risk management plan developed may propose the relocation of some communities and infrastructure.
This paper focuses on the shrinkage behavior of soil specimens involving sand, kaolinite, and kaolinite/sand mixtures subjected to desiccation under controlled conditions. Both, free and restrained shrinkage conditions are studied. The experiments show that pure soils do not curl upon unrestrained shrinkage; however, (under the same conditions) kaolinite/sand mixtures exhibited a marked curling. Furthermore, the mixture with the higher sand content broke through the middle of the sample after displaying a significant curling. Soils subjected to restricted shrinkage developed cracks with slight curling. To simulate the observed behavior, a mechanical model able to reproduce the detachment of the soil sample from the mold is proposed in this work and implemented in a fully coupled hydro-mechanical finite-element code. It is concluded that suction and differential shrinkage are key factors influencing the curling behavior of soils. The proposed framework was able to satisfactorily explain and reproduce the different stages and features of soil behavior observed in the experiments.
Natural Resource Management (NRM) is often conducted as a partnership between government and citizens. In Australia, government agencies formulate policy and fund implementation that may be delivered on-ground by community groups (such as Landcare). Since the late 1980s, over AUS$8b of Commonwealth investment has been made in NRM. However, quantitative evidence of environmental improvements is lacking. The NRM Planning Portal has been developed to (1) provide an online spatial information system for sharing Landcare and agency data; and (2) to facilitate NRM priority setting at local and regional planning scales. While the project successfully federates Landcare NRM activity data, challenges included (1) unstructured, non-standardized data, meaning that quantitative reporting against strategic objectives is not currently possible, and (2) a lack of common understanding about the value proposition for adopting the portal approach. Demonstrating the benefit of technology adoption is a key lesson for digital NRM planning. 相似文献
Doklady Earth Sciences - The results of an analysis of changes in the atmospheric air quality in Moscow during the lockdown period and the decline in business activity caused by the COVID-19... 相似文献
Geotectonics - The dunite–wehrlite–clinopyroxenite–gabbro massif in Eastern Chukotka, a key object for geodynamic reconstructions of the Vel’may terrane, which represents... 相似文献
Glacial tills are highly compressible soils composed of loosely cemented sandy silt particles. Their role, for instance, as initial filler materials in geo-technical projects along temperate glacier regions warrant a systematic evaluation of their compressive characteristics. As such, we carry out a series of onedimensional compression tests on re-compacted glacial till samples obtained from Tianmo Gully, Tibet, with the aims of evaluating their compressive behavior under controlled initial stress conditions. The yield stress was determined from the void ratio versus consolidation pressure(e-log) planes. Its compression and swelling behaviors were observed during the primary and secondary compressions of the consolidation tests. From the compression curves, a correlation can be found between the consolidation stress and the void index. In addition, we find that the compression curves of glacial tills collapse into a single curve when normalized by the compression index. The experimental results in this study provide a basic understanding of the compression characteristics of the glacial tills in Tibet, China. 相似文献
Chile has a rich, but poorly known history of placer gold mining. At present, this sector is almost nonexistent and there are some restrictions for its revival: disperse and partial information on existing resources and limited technical expertise to assess the potential of placer gold mine sites. This paper presents the background, methodology and results of the prioritization process of known prospects of this kind in Chile. This research was part of a publicly funded project aimed to incentivize the development of this industry. The ranking was carried out using the analytic hierarchy process, which allowed to include different quantitative and qualitative variables related to the economic potential, technical aspects, contextual viability and socioeconomic factors in the analysis. The results show that, despite the increasing relevance of environmental and community issues in mining development, the business potential and the economic/technical aspects are the main factors in the early selection of a site to advance in exploration and development activities. Both variables represented around 40% and 37% of weights in the final selection, respectively. In contrast, contextual viability and local socioeconomic impacts only accounted for the remaining 23%. This study also shows that the inclusion of experts with different backgrounds in the process enriches the analysis and does not significantly distort the final outcome of the prioritization. Finally, the relevance of using MCDM tools when assessing the attractiveness of mine sites for their development is highlighted, particularly when public funds for subsequent exploration activities are committed.
